Document Type

Article

Publication Date

12-7-2016

Publication Title

Dalton Transactions

Department

Chemistry

Abstract

Hydride attack at a ferric heme–NO to give an Fe–HNO intermediate is a key step in the global N--‐cycle. We demonstrate differential reactivity when six--‐ and five--‐coordinate ferric heme--‐NO models react with hydride. Although Fe–HNO formation is thermodynamically favored from this reaction, Fe–H formation is kinetically favored for the 5C case.

Comments

This is the Accepted Manuscript version of an article published in Dalton Transactions on December 7, 2016.

SI_FeHNO_R1.pdf (2883 kB)

Available for download on Thursday, December 07, 2017

Share

COinS